La2O3(210) 73.503 73.51117775 73.54460029
La2O3(211) 75.391 75.39955114 75.39955114
La2O3(114) 79.233 79.22643174 79.25985428 79.25985428 79.24314301 79.22643174
La2O3(212) 80.955 80.93098117
La2O3(105) 83.879 83.90558705 83.88887578 83.87216451 83.88887578
La2O3(300) 85.404 85.40960126 85.40960126
La2Zr2O7(111) 14.194 14.25301795 14.20288414 14.18617288 14.23630668 14.20288414
La2Zr2O7(222) 28.583 28.64142054 28.52444166 28.57457547 28.64142054 28.59128673
La2Zr2O7(400) 33.128 33.1868857 33.136优尔9 33.15346317 33.23701951 33.17017443
La2Zr2O7(331) 36.188 36.19491412 36.19491412 36.21162539 36.16149158 36.19491412
La2Zr2O7(511) 43.441 43.44760486 43.43089359 43.48102739 43.49773866 43.43089359
La2Zr2O7(440) 47.549 47.59199956 47.50844322 47.6254221 47.65884464 47.59199956
La2Zr2O7(622) 56.408 56.44897212 56.41554958 56.44897212 56.5158172 56.46568339
La2Zr2O7(444) 59.18 59.25646531 59.18962023 59.2063315 59.2063315 59.23975404
La2Zr2O7(800) 69.509 69.550607 69.46705066 69.51718446 69.56731827 69.53389573
La2Zr2O7(733) 71.38 71.40555786 71.35542405 71.38884659 71.38884659 71.42226913
La2Zr2O7(优尔) 76.245 76.2852484 76.30195967 76.30195967 76.26853713 76.26853713
La2Zr2O7(662) 76.78 76.78658647 76.78658647 76.78658647 76.90356535 76.82000901
La2Zr2O7(840) 79.169 79.22643174 79.1930092 79.17629793 79.24314301 79.22643174
La2Zr2O7(844) 88.527 88.55131983 88.55131983 88.51789729 88.5680311 88.51789729
图3.3不同反应时间产物的XRD图
图3.3是不同反应时间产物的XRD图,从图3.3可知在反应物与熔融盐比为1:3,反应温度为1000℃下分别在1h、3h、8h、9h、10h所得产物中除La2Zr2O7相以外还有ZrO2杂质相和La2O3杂质相的存在,这说明在这些条件下ZrO2和La2O3不能完全转化为La2Zr2O7。由图3.3中的1h、3h、8h、9h、10h曲线可以看出:随着反应时间的加长, ZrO2(-322)、ZrO2(-232)、ZrO2(040)、ZrO2(-313)、La2O3(203)、La2O3(210)、La2O3(211)、La2O3(300)等晶面渐渐消失;并且随着反应时间的继续加长到8h以后La2Zr2O7的衍射峰强度增加。 锆酸镧陶瓷粉的制备+文献综述(16):http://www.youerw.com/huaxue/lunwen_1876.html