聚苯胺杂化复合材料的合成及电化学性能研究

摘要以氮掺杂多孔碳（NMC）为基体与聚苯胺（PANI）制备的复合材料，是高性能超级电容器电极材料研究的热点。本文研究内容主要涉及两方面：在NMC@PANI复合材料基础上，研究分别添加不同浓度金属离子Ni2+、Co2+与酸共掺杂NMC@PANI，对复合材料微观形貌和电化学性能的影响；采用硫酸锰(MnSO4)和过硫酸铵(APS)，利用超声分散法、化学原位聚合法制备氮掺杂多孔碳@MnO2@PANI三元复合材料，考察其微观形貌和电化学性能。通过采用傅里叶转换红外光谱、X射线衍射、拉曼光谱、扫描电子显微镜等多种手段对复合材料结构进行表征，并采用电化学工作站以三电极体系，对材料电化学性能测试分析。73537

毕业论文关键词氮掺杂聚苯胺超级电容器金属离子二氧化锰

毕业设计说明书外文摘要

Title Synthesis and electrochemical performance of Ployaniline hybridization composite

Abstract

The composite material is a hotspot of high performance supercapacitor electrode materials research, which compounded by Nitrogen-doped porous carbon (NMC) as matrix and polyaniline (PANI)。 In this paper, the research mainly involves two aspects: the composite microstructure and electrochemical properties is influenced by which different concentrations of metal ions Ni2+ and Co2+ were added ,respectively, with acid co-doped NMC@PANI; Using MnSO4 and APS, the ternary composite of nitrogen-doped porous carbon @MnO2@PANI was synthesized through the ultrasonic dispersion method and chemical in-situ polymerization, then studying its morphology and electrochemical properties。 The composite structure were investigated by FTIR、XRD、Raman、SEM and other methods, and electrochemical capacitivetests were analyzed by electrochemical workstation。

Keywords Nitrogen-doped PANI Supercapacitor Metal ion MnO2

1 绪论 1

1。1超级电容器概述 1

1。2聚苯胺复合材料电化学性能研究 2

1。3碳基复合材料电化学性能研究 3

1。4三元复合材料电化学性能研究 4

1。5选题意义和研究内容 5

2 金属离子掺杂氮掺杂多孔碳@PANI复合材料的研究 6

2。1实验试剂与仪器 6

2。2复合材料的制备 7

2。2。1 Ni2+掺杂氮掺杂多孔碳@PANI复合材料的制备 7

2。2。2 Co2+掺杂氮掺杂多孔碳@PANI复合材料的制备 8

2。3表征与测试 8

2。3。1 FTIR表征 8

2。3。2 XRD表征 8

2。3。3 SEM表征 8

2。3。4电化学测试 8

2。4结果与讨论 9

2。4。1 FTIR分析 9

2。4。2 XRD分析 10

2。4。3 SEM分析 10

2。4。4电化学分析 11

3 氮掺杂多孔碳@PANI@MnO2复合材料的研究 16

3。1实验试剂与仪器 16

3。2复合材料的制备聚苯胺杂化复合材料的合成及电化学性能研究:http://www.youerw.com/huaxue/lunwen_83922.html