毕业设计（论文）题目：

水性金属离子交联剂的制备与性能

一、毕业设计（论文）内容及要求（包括原始数据、技术要求、达到的指标和应做的实验等）

1．了解交联剂的种类

2．了解交联剂在涂料中的应用

3．了解交联剂在涂料中的作用机理

4．掌握金属离子交联剂的制备方法及其性能测试

5．掌握金属离子交联涂料的制备及性能测试

二、完成后应交的作业（包括各种说明书、图纸等）

1.水性金属离子交联剂的制备与表征

2.水性金属离子交联剂的性能测试

三、完成日期及进度

1、2017年3月~4月：水性金属离子交联剂的制备

2、2017年4月~5月；水性金属离子交联剂性能测试和表征

3、2017年5月~6月；论文书写，准备答辩

四、主要参考资料（包括书刊名称、出版年月等）:

[1] D. Philp; J. F. Stoddart. Self-Assembly in Natural and Unnatural Systems[J]. Angewandte Chemie(International Edition), 1996, 35(11): 1154-1196.

[2] A. Anthony, M. Jaskolski, A. Nangia, et al. 17,17-Ethylenedioxyandrost-4-ene-3,6-dione and

17,17-Ethylenedioxyandrosta-1,4-diene-3,6-dione[J].Acta Crystallographica.Section C, 1998, 54(12): 1894-1898.

[3] D. F. Evans, H. Wennerström. The colloidal domain : where physics, chemistry, biology, and technology meet[M]. New York:John Wiley & Sons, 1999.

[4] M. N. Jones, D. Chapman. Micelles, monolayers and biomembranes[M]. New York: John Wiley & Sons; 1995.

[5] J. M. Lehn. Toward self-organization and complex matter[J]. Science, 2002, 295(5564): 2400-2403.

[6] G. S. Hanan, D. Volkmer, U. S. Schubert, et al. Coordination Arrays: Tetranuclear Cobalt(II) Complexes with [2×2]-Grid Structure[J]. Angewandte Chemie(International Edition), 1997, 36(17): 1842-1844.

[7] G. S. Papaefstathiou, L. R. MacGillivray. Inverted metal-organic frameworks: solid-state hosts with modular functionality[J]. Coordination Chemistry Reviews, 2003, 246(1): 169-184.

[8] J. M. Lehn. Supramolecular polymer chemistry - scope and perspectives[J]. Polymer International, 2002, 51(10): 825-839.

[9] A. Kunitsugu, S. Tadashi. Improvement of healing treatment with NaNO3 for a passivated iron electrode covered with an ultrathin polymer coating to prevent iron corrosion in some solutions containing aggressive anions[J]. Corrosion Science, 2011, 53(12): 4152-4158.

[10] A. Paszternák, I. Felhősi, Z. Pászti, et al. Surface analytical characterization of passive iron surface modified by alkyl-phosphonic acid layers[J]. Electrochimica Acta, 2010, 55(3): 804-812.

[11] F. E. Heakal, A. S. Fouda, M. S. Radwan. Inhibitive effect of some thiadiazole derivatives on C-steel corrosion in neutral sodium chloride solution[J]. Materials Chemistry and Physics, 2011, 125(1): 26-36.

[12] S.Hong,W.Chen,H.Q.Luo,N.B.Li.Inhibition effect of 4-amino-antipyrine on the corrosion of copper in 3wt% NaCI solution[J].corrosion science,2012,57:270-278. [13] A. Kunitsugu, S. Tadashi. Self-assembled monolayers of carboxylate ions on passivated iron for preventing passive film breakdown[J]. Corrosion Science, 2004, 46(2): 313-328.

[14] K. Aramaki, T. Shimura. Prevention of passive film breakdown and corrosion of iron in 0.1 M KClO4 with and without Cl by covering with an ultrathin

two-dimensional polymer coating and healing treatment in 0.1 M NaNO3[J]. Corrosion Science, 2010, 52(9): 2766-2772.

[15]A. Paszternák, I. Felhősi, Z. Pászti,L. Nyikos.surface analytical characterization of passive iron surface modified alkyl-phos phonic acid layers[J].Electochimica Acta.2010,55,804-812.

[16]F.EI-Taib Heakal,A.S.Foude,M.S.Redwan.Inhibitive effect of some thiadia-zole derivative on C-steel corrion in neutral sodium chloride solution[J].Materials Chemisty and Physics.2011,125,26-36.