氧化铒耐高温陶瓷研制及其热辐射特性研究

摘要热光伏发电（TPV）是一种新型的热电转化装置，具有能量转换效率高，能量来源广，可靠性高，无污染等优点，但实际效率低成为了限制其发展的主要因素之一。作为热光伏发电系统的关键部件，选择性辐射器的性能好坏对系统整体效率影响很大。氧化铒耐高温陶瓷是一种与锑化镓（GaSb）热光伏电池匹配良好的材料。本文主要研究基于氧化铒的耐高温陶瓷的制备方法，采用固相合成法，经配料，混合，造粒，压制成型，烧结等步骤合成了满足条件的氧化铒耐高温陶瓷样品。同时本文对制取的氧化铒陶瓷样品进行热辐射特性测量，得到其光谱辐射率，并探究得到了不同氧化铒含量以及氧化铝纤文含量对样品选择性辐射特性的影响。21458
关键词热光伏发电选择性辐射器氧化铒陶瓷
毕业论文设计说明书（论文）外文摘要
Title     The preparation of erbium oxide high-temperature ceramic and its emissivity research
Abstract
Thermalphotovoltaic (TPV) ,which is a new type of thermoelectric conversion device, has the advantages of high energy conversion efficiency, wide energy source, high reliability and no pollution. but the low actual efficiency has become one of the major factors limiting its development. As a key component of the thermal photovoltaic power generation system, the performance of selective emitters has a great influence on overall system efficiency. Erbium oxide high-temperature ceramic is a kind of materials well matched with gallium antimonide (GaSb) thermal photovoltaic cells. This paper mainly studies the preparation method of high temperature resistant ceramic based on erbium oxide,and synthesize qualified Erbium oxide high-temperature ceramic using the method of solid phase synthesis after compounding, mixing, granulation, pressure molding and sintering steps . Meanwhile ,the paper measeures thermal radiation characteristics of erbium oxide ceramic samples, obtains their spectral emissivity and explore the effect of the different erbium oxide content and alumina fiber content on selective radiation characteristics of the sample.
Keywords： Thermal photovoltaic Selective emitter Erbium oxide Ceramics
目   次
1 绪论    1
1.1 研究背景及意义    1
1.2 研究现状    2
1.3 氧化饵耐高温陶瓷的制备方法    4
1.3.1 固相合成法    4
1.3.2 液相合成法    4
1.4 本文的主要工作    5
2 氧化铒耐高温陶瓷的制备    6
2.1 配料    6
2.2 混合    7
2.3 造粒    8
2.4 压制成型    9
2.5 烧结    10
2.6 烧结过程变形及开裂控制    12
3 耐高温氧化铒陶瓷的热辐射特性研究    13
3.1 概述    13
3.2 测量原理及装置    13
3.2.1 积分球的基本构成    13
3.2.2 积分球工作原理    13
3.2.3 积分球反射测量原理    14
3.3 测量结果    16
3.4 实验分析和讨论    20
3.4.1 样品光谱辐射率曲线对比分析    20
3.4.2 分析结果讨论    21
3.5 本章小结    22
结论    23
致谢    24
参考文献25
1 绪论氧化铒耐高温陶瓷研制及其热辐射特性研究:http://www.youerw.com/cailiao/lunwen_13672.html