水性氨基醇酸树脂涂料的制备研究

摘要水性醇酸树脂成本低、无污染、涂膜综合性能好，因而被广泛应用于各个领域。实验中采用醇解法合成了水性醇酸树脂。用红外光谱（IR)对产物进行了表征。选用蓖麻油、亚麻油、三羟基甲基丙烷、偏苯三酸酐为主要原料合成水性醇酸树脂。采用环氧树脂改性多元醇，然后以改性多元醇醇解植物油，再酯化缩聚、羟基化、中和的方法合成环氧改性水性醇酸树脂。以自制水性醇酸树脂和氨基树脂配合制备水性氨基醇酸树脂漆，氨基树脂和醇酸树脂的配比1:3，烘烤温度为160 ℃。对制备的水性氨基醇酸树脂烘漆进行了耐酸性、耐碱性、耐盐性、耐水解性等性能的测试，各项性能均接近或达到国家标准。20686
关键词：水性醇酸树脂环氧树脂水性氨基醇酸树脂漆
毕业论文设计说明书（论文）外文摘要
Title      Preparation and Study of waterborne amino-alkyd paint
Abstract
Water-borne alkyd resin is wildly used in various fileds because of its low cost,pollution free,excellent properties.Alkyd resin was synthesized by Alcohol solution method.IR was applied to characterize the structure of the product.Castor oil , Linseed oil, trimethylolpropane and trimellitic anhydride were used as the main raw matterails to synthesize the water-borne alkyd resin.Water-based epoxy modified alkyd resin was synthesized through alcoholysising vegetable oil by Polyols which modified by epoxy resin,followed by esterification condensation,carboxylation and neutralized by salt.Waterborne amino-alkyd resin baking coatings was prepared by waterborne alkyd resin and high methyl ether amino resin,ratio between amino resin and waterborne alkyd resin is 1:3,baking temperature is 160℃。At last the performences of waterborne amino-alkyd resin baking coating such as acid resistance,alkali resistance, salt tolerance and resistance to hydrolysis were investigated, and these performence are all close to or reach the national standard.
Key words: Water-borne alkyd resin epoxy waterborne amino-alkyd resin baking coatings
目次
1 绪论    1
1.1 课题研究背景    1
1.2 醇酸树脂的概述    1
1.2.1 醇酸树脂水性化技术    1
1.2.2 水性醇酸树脂国内外研究现状    2
2 水性醇酸树脂的制备    5
2.1 主要实验仪器和试剂    5
2.2 实验装置图    6
2.3 实验流程    6
2.3.1 水性醇酸树脂的合成反应    6
2.3.2 反应步骤见下表    8
2.4 水性醇酸树脂制备工艺讨论    9
2.4.1 合成温度的选择    9
2.4.2 催化剂用量选择    10
2.4.3 单元酸的选择    12
2.5 红外光谱测试    13
3 双酚A改性水性醇酸树脂    16
3.1 实验试剂及仪器    16
3.2 实验装置图    17
3.3 实验流程    17
3.3.1 改性水性醇酸树脂的制备    17
3.4 结果与讨论    17
3.4.1 双酚A与苯甲酸用量的选择    17
3.4.2 油的选择    18
3.4.3 酸值走势    18
3.4.4 红外分析    18
4 环氧树脂改性水性醇酸树脂    20
4.1 实验部分    20
4.1.1 实验仪器设备和药品    20
4.1.2 实验装置图    21

4.1.3 实验原理    21
4.1.4 实验步骤    21 水性氨基醇酸树脂涂料的制备研究:http://www.youerw.com/huaxue/lunwen_12560.html