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摘要超级电容器又称电化学电容器，是一种介于电池与传统静电电容器之间的新型能量储存器件，具有功率密度大、比电容高、瞬间释放电流大、充放电效率高、充电时间短、循环寿命长等特性，近年来受到广泛关注并得到快速发展。超级电容器的性能主要取决于电极材料，因此对于电极材料的研究一直是该领域主要的研究内容。本实验围绕碳纳米管巴基纸/导电聚合物复合电极的制备、导电聚合物对材料形貌和电化学性能的影响及其机理进行了探索和讨论。首先采用抽滤法制备碳纳米管巴基纸，再采用脉冲法制备聚吡咯修饰巴基纸。采用扫描电子显微镜和光学显微镜对材料形貌、成分进行表征；采用伏安循环法、恒电流充放电测试等方法讨论所制备材料用作超级电容器电极的电化学性能。结果表明，聚吡咯修饰的巴基纸其电化学性能有明显提高。9372
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关键词 聚吡咯 巴基纸 超级电容器 复合电极
毕业设计说明书（论文）外文摘要
Title The preparation of the conductive polymer decorated Buckypaper
Abstract
Supercapacitors known as electrochemical capacitors, have been recognized as a new type of energy storage devices that fill the gap between batteries and conventional capacitors. Supercapacitors have been rapidly developed in recent years due to their high specific capacitance, high power density, a short time of charge, the charge-discharge efficiency and long cycle life. The performance of supercapacitors is largely depended on the electrode materials. As a result, the electrode materials attract a lot of attention around scientist all over the world.Our study is focused on the preparation of the conductive polymer decorated buckypaper and their effect and mechanism. Firstly , we prepareed the buckypapers by vacuum filtration method and then a pulsed potentio amperometric polymerization was performed in an aqueous to coat polypyrrole(PPy) onto the carbon nanotubes network of buckypaper.The morphology of the buckypaper was obsered with Scan Electron Microscope(SEM),Opitical microscopy characterization was carried out on a Microscope. And the electrochemical measurement,including cyclic voltammetry(CV) and galvanostatic charge/discharge tese were performanced on an Autolab.the result demonsrates that conductive polymer decorated buckypaper can be an excellent candidate electrode materials for high performance supercapacitors.
Keywords Polypyrrole buckypaper Supercapacitor Composite Electrode
目 次
1 引言 1
1.1 超级电容器的简介 1
1.1.1 超级电容器的概述1
1.1.2 超级电容器的工作原理1
1.1.3 超级电容器电极材料的研究现状2
1.2 碳纳米管巴基纸的简介3
1.2.1 碳纳米管巴基纸的概述3
1.2.2 碳纳米管巴基纸的制备4
1.3 导电聚合物的简介 5
1.3.1导电聚合物概述5
1.3.2 导电聚合物的导电原理6
1.3.3导电聚合物作为超级电容器电极材料6
1.3.4 聚吡咯（PPy）7
1.4本文的研究思路和内容8
2 实验部分 9
2.1 CNT巴基纸的制备 9
2.1.1 药品与仪器9
2.1.2 CNT预处理9
2.1.3 巴基纸的制备10
2.1.4 聚合物修饰巴基纸的制备10
2.2 表征与分析10
2.2.1巴基纸的形貌表征10