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摘要实验通过合成预聚物单体和含能聚合物单体，两者通过超声法混合后将聚合物单体制备为含能墨水，并注入三文打印快速成型系统的针筒内，在硅板，损坏的半导体桥和完整的半导体桥基底上打印含能元件，在紫外光的照射下固化得到含能材料，并且进一步研究含能材料的起爆性能。有别于以往的直接将固体含能材料加入溶剂中溶解后来制备含能墨水的方法相比，本实验研究的含能墨水制备方法的优点在于研究过程中使墨水具有较好的流动性，并且改进和完善了因为溶剂挥发的原因从而导致了打印设备中针筒堵塞的问题，避免了设备的损坏和文修。25203
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关键词：三文打印快速成型技术；含能墨水；紫外光固化
毕业论文设计说明书外文摘要
Title Design and synthesis of energetic monomer by Inkjet printing
Abstract
Energetic prepolymer monomer and energetic monomer have been rationally designed and synthesized successfully in this paper. Energetic ink, prepared by the monomers mentioned above , was injected into the three dimensional printing (3DP) rapid prototyping system to acquire energetic patterns on the base of silicon plate, damaged semiconductor bridge and intact semiconductor bridge. The energetic films were obtained successfully after UV curing and its electrical explosion performance was further investigated. Compared with that of conventional energetic ink made by the addition of solid energetic materials into the solvent, the energetic ink synthesized in this paper possessed better liquidity. In addition, the problem that the injection needle was liable to be blocked because of volatilizing of solvent was solved effectively at the same time，avoiding damage and service of the device.
Key words: Three dimensional printing (3DP) rapid prototyping technology; Energetic ink ; UV curing
目 录
1 绪论 1
1.1 研究背景 1
1.2含能材料的概述 1
1.2.1 含能材料 1
1.2.2 含能聚合物 2
1.2.3 含能聚合物的分类 2
1.2.4 含能聚合物单体的合成方法 3
1.3 快速成型技术概述 4
1.3.1 快速成型技术 4
1.3.2 喷墨打印技术 5
1.4 紫外光固化墨水 6
2 实验部分 8
2.1.聚合原理 8
2.2实验设计 9
2.3实验仪器以及所用试剂 9
2.4实验步骤 10
2.4.1 含能预聚物单体的合成 10
2.4.1.1 3-苦基丙炔的合成 10
2.4.1.2 钯铜催化条件下端炔的对称偶联反应 11
2.4.1.3 1，6-二苦基-2，4-己二炔的合成 11
2.4.2 含能预聚物单体的合成方案改进........13
2.4.2.1 碱性盐条件下升温回流合成3-苦基丙炔.13
2.5讨论 15
3 含能墨水的喷墨打印快速成型 16
3.1 含能墨水的配方设计 16
3.2 含能薄膜的制备 18
3.2.1 含能墨水的准备 18
3.2.2 含能墨水的喷墨打印快速成型 19
3.3 实验小结 20
致 谢 22