改性炭黑-白炭黑双相粒子对天然胶性能影响研究
摘要随着“绿色轮胎”概念的提出，轮胎行业以及橡胶工业对轮胎胎面胶提出了新的要求-在不降低磨耗性能使用寿命等前提下降低滞后损失、提高燃油经济。本课题通过机械共混方法以Si-69改性炭黑-白炭黑双相粒子，将改性填充剂用以补强天然橡胶硫化胶并通过撕裂、磨耗、老化、疲劳、拉伸等试验比较改性粒子与传统炭黑粒子填充效果。结果表明：CSDPF-NR的结合橡胶含量高于NR-N330的结合橡胶；随CSDPF含量的增加，NR胶料的撕裂强度、疲劳寿命增加，拉伸强度出现最大值。而磨耗性能下降，表明CSDPF的磨耗性能没有N330好，CSDPF与N330具有协同效应，当CSDPF/N330为15/45时，硫化胶料的综合性能最好。63628
毕业论文关键词 炭黑-白炭黑双相粒子 天然橡胶 Si-69 拉伸强度 撕裂强度 耐磨性能
毕业设计说明书（论文）外文摘要
Title The research of modified carbon black-silica dual-phase Particles’s impact on the performance of nature rubber Abstract With the proposal of the concept of “green tire”, the tire industry and rubber industry put forward new demands for tire tread rubber- lower hysteresis loss and improve fuel economy without reducing the wear performance and using life.Of this subject Si-69 is used to modify carbon black - silica dual-phase particles by mechanical blending method. The modified filler is used for the reinforcement of natural rubber vulcanizates. Tear, wear, aging, fatigue and tensile trials to compare modified particles with the traditional carbon black particles filling effect. The results showed that: the combination of the rubber content of CSDPF-NR NR-N330 higher than the combination of rubber; with the the content increases CSDPF, NR rubber compound tear strength, fatigue life increases, come to the maximum tensile strength. Wear performance degradation, shows the wear performance of the CSDPF is worse than N330, CSDPF and N330 have a synergistic effect when CSDPF/N330 is 15/45, it has the best overall performance of the vulcanization of rubber.
Keywords Carbon black - silica dual-phase particles natural rubber Si-69 Tensile strength Tear strength wear resistance
1 引言 1
1.2课题背景 1
1.2.1炭黑 2
1.2.2白炭黑 3
1.2.3其它新型填料（石墨烯，碳纳米管） 5
1.2.4炭黑-白炭黑双相粒子 5
1.2.5炭黑-白炭黑的生产方法 5
1.2.6 炭黑-白炭黑补强原理 6
1.2.7 Si-69 6
1.2.8 应用 6
1.3 课题内容及研究手段 7
2 实验部分 7
2.1 原材料 7
2．2 实验设备及测试仪器 8
2.3 CSDPF的改性和表征 8
2.3.1红外表征 8
2.3.2 TG表征 8
2.3.3 CSDPF/N330/NR硫化胶的制备 9
2.3.4 CSDPF/N330/NR性能测试 9
2.4 结果与讨论 11
2.4.1炭黑-白炭黑双相粒子改性前后红外光谱图