3）选取乙酰乙酸乙酯、苯胺、苯甲醛为反应物，SalenZn为催化剂，催化剂摩尔量为底物的4%，二氯甲烷为溶剂，得到的β-氨基酮衍生物的产率为88%。［20］
参考文献
[1]Kai Gong，Dong Fang，Hua-Lan Wang. Basic Functionalized Ionic Liquid Catalyzed One-pot Mannich-type Reaction:Three Component Synthesis ofb-Amino Carbonyl Compounds，Springer-Verlag，China. 2007，138: 1195~1198.
[2]Zhang Hao，Huang Yunyun，Zhao Jianbin. The research on Mannich reaction catalyzed by Cu(OTf)2 [J]. gdchem，2012，39(236): 59~60.
[3]Xiao Shangyou，Zeng Qingwen，Chen Zhitao. Mannich Reactions of Aromaitic Aldehydes with Aromatic Amines and Aromatic Ketones[J]. JournaL of Chongqing University，2000，23(1): 102~104.
[4] Xiao Liwei，Kong Jie，Zhou Qiuxiang. One Pot Synthesis of β-Amino Ketone Dericatives CataLyzed by Polystyrene-supported Ferric Chloride[J]. Chineses Journal of Applied Chemistry，2014，31(6): 716~720.
[5]Guo PingLu，Chun Cai. Mannich reactions catalyzed by percholoric acid in Trition X10 aqueous micelles[J]. CataLysis Communications，2010(11): 745~748.
[6]吴璇，李文思，李振江．氨基磺酸催化的Mannich反应合成β-氨基酮[J]. 化学试剂，2008，30(4): 277~279.
[7]孟团结，辛丽，王进贤．碘催化芳香酮、芳香醛和芳香胺的Mannich反应：三组分“以锅法”[M]. 商丘师范学院学报，2005，22(2):101~103.
[8]Wang Liming，Han Jianwei，Sheng Jia. Yb(OTf)3 Catalyzed Mannich Reaction of Acetophenone with Aromatic Aldehydes and Aromatic Amines: Three Component one-pot Sythensis of β-Amino Ketone Derivatives[J]. Chinese J org Chem，2005，25(5): 591~594.
[9]严文君，王丽，李娜．ALCL3催化三组分Mannich反应“一锅法”合成β-氨基酮衍生物[M]. 宜宾学院学报，2010，10(6): 68~70.
[10]Chen JunLi, Xie Zhengfeng, Xing Ye. Mannich Reaction of Acetophenone  Aromatic Aldehydes and Aromatic Amines Catalyzed by Tungstophosphoric Acid in Water[J]. Chinese Jorg Chem，2011，33(10): 1714~1718.
[11]韩波，祁国庆，魏清渤．Keggin型硅钨酸高效催化一锅法合成β-氨基酮衍生物[J]. Chemical Reagents，2012，34(8): 753~755.
[12]史兰香，张宝华，梁宏伟等. 脯氨酸催化的直接不对称Mannich反应[M]. 河北科技大学学报，2005，26(3):203~207.
[13]Huang Bichun，Huang Zhongtao. Researches in ionic liquids and their application in catalysis[J]. Industrial catalysis，2003，11(2): 1~6.
[14]Zhang Puyu，Lou Shuai，Jin Linyu. Progress in Research on Applications of Ionic Liquids[J]. Fine Chemicals，2005，22(5): 324~327.
[15]Tao Chang，Leqin He，Li Bian. Bronsted acid-surfactant-combined catalyst for the Mannich reaction in water[J]. Royal society of Chemistry，2014(4): 727~731.
[16]方东，刘祖亮. 新型功能化离子液体催化水相Mannich反应[M]. 南京航空航天大学学报，2007，39(4): 541~543.
[17]刘宝友，许丹倩，罗书平等. Bronsted酸离子液体催化的醛、酮、胺三组分Mannich反应[M]. 化工学报，2004，55(12): 2043~2046.
[18]Ezzat Rafiee，Sara Eavani. H3PW12O40 supported on silica-encapsulated c-Fe2O3nanoparticLes: anovel magnetically-recoverable catalyst for three-component Mannich-typereactions in water[J]. Green Chemistry，2011，12，2116~2122.
[19]Min Zhang, Biao Xiong，Wei Yang. Highly efficient one-pot,three-component synthesis of β-aminoketones catalyzed by Fe(O2CCF3)3[J]. Synthetic Communications，2012，42，2831~2843.
[20]MeiWu，Huanwang Jing，Tao Chang. Synthesis of β-amina carbonyl compounds via a Mannich reaction catalyzed by SalenZn complex[J]. Catalysis Communications 2007，8，2217~2221. β-氨基酮衍生物文献综述和参考文献(4):http://www.youerw.com/wenxian/lunwen_34288.html