基于In，Gd共掺杂的BaCeO3电解质单电池的组装与表征
毕业论文关键词：质子导体;铈酸钡基电解质;固体氧化物燃料电池；
Abstract Compare with the solid oxide fuel cell (SOFC), Proton conductors fuel cell (PCFC)has lower activation energy and proton conductivity of preparation process and if thebattery cathode matching problem is solved, so in an atmosphere of hydrogen and hydrocarbon, Proton conductors fuel cell (PCFC) conducts electricity better than solid oxide fuel cell (SOFC) is superior. Not only that, the fuel cell of Proton conductor operating temperature (350~600℃) than the working temperature of the solid oxide fuel cell (700~1000℃), can reduce the requirement for hardware devices. Many fuel cell of Proton conductor, cerium and barium base for solid oxide fuel cell electrolyte Proton conductors are particularly concerned. BaCeO3 has a higher electrical conductivity of Proton conductr, currently Gd3+ doped BaCeO3 is by far the highest reported of Proton conducting materials, become a hot spot in SOFC electrolyte. This experiment in addition to outside the barium cerium-doped Gd3+, also added In3+, this is because the In3+ can significantly improve cerium and barium chemical stability and sintering activity and adding ZnO to lower the reaction temperature. Selected traditional Ni based as the anode, a selection of the latest reported BaCo0.4Fe0.4Zr0.1Y0.1O3 with perovskite structure (BCFZY0.1) as a cathode, sintering temperature in a single step, preparation of Ni-base/BCIGO721/BCFZY0.1 battery with a sandwich structure.This thesis is pided into three parts, the first part is the preparation needed for thecell structure in the early powder, were prepared by reaction sintering of BCIGO721 electrolytes, ammonia was prepared by coprecipitation NiO and mixed BCIGO721 pressed powder as an anode substrate cathode materials prepared by sol-gel BaCo0.4Fe0.4Zr0.1Y0.1O3-δ (BCFZY0.1), by XRD and SEM tests can analysis out this threespecies material is can as battery of structure; second part is preparation single battery structure, using total pressure method in directly made has sandwich structure of fuel battery health billet, after sintering and impregnated get full of Proton conductor fuel battery, and through XRD and the SEM to observation battery of structure and real phase; third part is package battery for test, according to the result of test，we will adjust the parts of the cell.
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