图2采用M-1方法测得的配体质谱图

3。1。2 配体红外光谱

表1 配体的实验与计算振动频率

编号 理论值(cm-1) 强度 实验值(cm-1) 振动来源

1 96。62 20。3566 ωN26H29+ωC17H22+ωR1+ωC28O31

2 28。43 0。9884 ωC17H22+ωR1

3 30。90 0。0018 ωR1+ωR2+ωR3+ωR4

4 36。47 1。3838 δN21N26

5 47。03 0。8004 τR1+τR2+τR3+τR4+τN21N26

6 88。48 0。6424 τR1+τR2+τR3+τR4+τN21N26+ τC17H22

7 109。16 1。6352 τR1+τR2+τR3+τR4+τN21N26

8 119。78 2。4017 τR1+τR2+τR3+τR4+τN21N26

9 127。30 3。0193 ρC17N21

10 170。43 0。2240 τR1+τR2+τR3+τR4+τC17H22

11 176。15 0。0483 ρN21N26+ρR2

12 238。83 0。0035 ωR2+ωR3+ωR4

13 254。89 2。3797 τR1+τR2+τR3+τR4+τ N26H29

14 270。15 0。3770 ρR4+ρR2

15 287。72 23。3667 ρR1+ρC28O31

16 334。33 0。6433 τR2+τR3+τR4+ τN26H29+ τC17H22

17 387。54 3。0241 νC28C30+νR1+νR3

18 387。85 22。1085 τR1+τN26H29

19 399。30 0。9374 ρR2+ρR3+ρR4+ρN21N26

20 412。54 0。3088 δR1+δR2+δR3+δR4

21 421。30 4。4001 τR1+τR2 +τR4+τN26H29

22