摘要：本文概述了氧化亚铜(Cu2O) 的应用及氧亚化铜超细颗粒的特性、工艺进展、表征手段；研究以企业现有产品氯化亚铜为原料，采用液相还原法制备高纯纳米氧化亚铜粉体小试工艺，为企业现有产品开发下游高端产品，采用XRD、EMS、IR对产物进行了表征。液相沉淀法的制备成本低、设备简单、操作易行，化学计量性良好，而且产品的粒度范围有较宽的分布，这确保了氧化亚铜晶粒可控性。依据小试工艺和查阅到的相关参数，然后再在物料衡算、热量衡算基础上进行设备选型、车间布置，最后经CAD软件绘制了工艺流程图、车间布置图。以此来为企业的工艺设计技术提供贮备。 57443

毕业论文关键词：液相还原法；氧化亚铜；表征 ；工艺设计

Preparation of cuprous oxide reduction of small test and the designation of the Production

Abstract: This article outlines the characteristics of cuprous oxide (Cu2O) and the application of ultrafine particles in cuprous oxide, technology advances characterization techniques;research the company's existing products cuprous chloride as raw materials were prepared by liquid-phase reduction method of high purity nano cuprous oxide powder small test technology for the company's existing product development downstream of the high-end products, the use of XRD, EMS, IR of the product was characterized. Low production cost precipitation method, the equipment is simple, easy operation, good stoichiometry and grain size range of products has a wider distribution, which ensures that the cuprous oxide grain controllable. Based on small scale process and to consult relevant parameters, and then the material balance, heat balance for device selection based on plant layout, and finally by the CAD software to draw a flow chart, plant layout. In order to provide a reserve for the design technology of business process.

Key Words: Liquid phase reduction method ; Cuprous Oxide；Characterization ; Technological Design

目  录

1引言 6

1.1氧化亚铜的生产工艺 6

  1.1.1氧化亚铜的基本生产工艺 7

  1.1.2氧化亚铜国内外研究现状 7

1.2立题依据 8

1.3液相还原法法制备氧化亚铜的工艺简介 8

        附图1.3 氧化亚铜制备流程图 8

1.4原料性质 9

  1.4.1氯化亚铜 9

  1.4.2双氧水 9

  1.4.3氯化氢 9

  1.4.4硼氢化钾 10

2小试实验 11

2.1氧化亚铜的制备 11

  2.1.1前言 11

  2.1.2实验部分 12

  2.1.3 实验原理及方法 13

  2.1.4样品的表征 14

2.2结果与讨论 14

  2.2.1 反应温度对产物的影响 14

  2.2.2 反应时间对产物的影响 17

      2.2.3  NaOH浓度对产物的影响 20

  2.2.4 不同表面活性剂对产物的影响 21

  2.2.5  不同PVP量对产物的影响