金簇物配体的设计合成研究
毕业论文关键词：金属簇合物；配体；合成
Abstract This thesis firstly introduces the special nature and performance of atomic clusters, and also noted the status of its application and the main problems and technical challenges in its synthesis。 Meanwhile, the advantages of sulfur and phosphorus atoms Clusters have been highlighted here。 Several major methods of preparing clusters, including solid phase reaction method, liquid-phase reaction method and hydrothermal reaction, and their respective advantages and disadvantages were also introduced here。 The metal clusters as an important branch of atomic clusters attracted more and more attention of chemists。 The application of metal clusters, especially the gold clusters, in biology is playing a vital role for the entire field of biology。 Improving the performance of gold clusters in the field of biology and developing more excellent properties of gold clusters become a major difficult problem。 But, the application of suitable ligands, such as N, P-ligands, will improve the solubility of gold clusters in both water and oil, and finally effect its application in biology。 This thesis will focus on the design and synthesis of the N, P-ligands of gold clusters。 According to the literature, we design the target molecular and the routes of its synthesis。 The desired product was obtained by improving and developing the synthetic methods。
Key points: Metal Cluster；Ligand；Synthesis
目 录
目 录 III
第一章 绪 论 1
1。1引言 1
1。2簇合物的分类和应用现状 1
1。2。1簇合物的分类 1
1。2。2簇合物的应用现状 2
1。3W/S/Cu簇合物的制备方法 4
1。3。1固相反应法 4
1。3。2 液相反应 4
1。3。3 水(溶剂)热反应 5
1。4重要的原子簇化合物及合成 6
1。4。1含羰基配位体的金属原子簇化合物 6
1。4。2全碳分子 8
1。4。3硫簇化合物 8
1。6 配位化学的发展 10
1。7 本课题研究的目的，意义及研究内容 12
1。7。1 本课题的研究目的及意义 12
1。7。2 本课题的研究内容 13
第二章 实验部分 14
2 。1实验试剂及实验仪器 14
2。1。1实验所用试剂： 14
2。1。2实验所用仪器： 14
2。2 样品的制备 14
2。2。1 BBTA的合成 14
2。2。2 a-TBTP的合成 15
2。2。3 TBTP的合成 16
2。3样品表征 16
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