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    3)选取乙酰乙酸乙酯、苯胺、苯甲醛为反应物,SalenZn为催化剂,催化剂摩尔量为底物的4%,二氯甲烷为溶剂,得到的β-氨基酮衍生物的产率为88%。[20]
    参考文献
    [1]Kai Gong,Dong Fang,Hua-Lan Wang. Basic Functionalized Ionic Liquid Catalyzed One-pot Mannich-type Reaction:Three Component Synthesis ofb-Amino Carbonyl Compounds,Springer-Verlag,China. 2007,138: 1195~1198.
    [2]Zhang Hao,Huang Yunyun,Zhao Jianbin. The research on Mannich reaction catalyzed by Cu(OTf)2 [J]. gdchem,2012,39(236): 59~60.
    [3]Xiao Shangyou,Zeng Qingwen,Chen Zhitao. Mannich Reactions of Aromaitic Aldehydes with Aromatic Amines and Aromatic Ketones[J]. JournaL of Chongqing University,2000,23(1): 102~104.
    [4] Xiao Liwei,Kong Jie,Zhou Qiuxiang. One Pot Synthesis of β-Amino Ketone Dericatives CataLyzed by Polystyrene-supported Ferric Chloride[J]. Chineses Journal of Applied Chemistry,2014,31(6): 716~720.
    [5]Guo PingLu,Chun Cai. Mannich reactions catalyzed by percholoric acid in Trition X10 aqueous micelles[J]. CataLysis Communications,2010(11): 745~748.
    [6]吴璇,李文思,李振江.氨基磺酸催化的Mannich反应合成β-氨基酮[J]. 化学试剂,2008,30(4): 277~279.
    [7]孟团结,辛丽,王进贤.碘催化芳香酮、芳香醛和芳香胺的Mannich反应:三组分“以锅法”[M]. 商丘师范学院学报,2005,22(2):101~103.
    [8]Wang Liming,Han Jianwei,Sheng Jia. Yb(OTf)3 Catalyzed Mannich Reaction of Acetophenone with Aromatic Aldehydes and Aromatic Amines: Three Component one-pot Sythensis of β-Amino Ketone Derivatives[J]. Chinese J org Chem,2005,25(5): 591~594.
    [9]严文君,王丽,李娜.ALCL3催化三组分Mannich反应“一锅法”合成β-氨基酮衍生物[M]. 宜宾学院学报,2010,10(6): 68~70.
    [10]Chen JunLi, Xie Zhengfeng, Xing Ye. Mannich Reaction of Acetophenone  Aromatic Aldehydes and Aromatic Amines Catalyzed by Tungstophosphoric Acid in Water[J]. Chinese Jorg Chem,2011,33(10): 1714~1718.
    [11]韩波,祁国庆,魏清渤.Keggin型硅钨酸高效催化一锅法合成β-氨基酮衍生物[J]. Chemical Reagents,2012,34(8): 753~755.
    [12]史兰香,张宝华,梁宏伟等. 脯氨酸催化的直接不对称Mannich反应[M]. 河北科技大学学报,2005,26(3):203~207.
    [13]Huang Bichun,Huang Zhongtao. Researches in ionic liquids and their application in catalysis[J]. Industrial catalysis,2003,11(2): 1~6.
    [14]Zhang Puyu,Lou Shuai,Jin Linyu. Progress in Research on Applications of Ionic Liquids[J]. Fine Chemicals,2005,22(5): 324~327.
    [15]Tao Chang,Leqin He,Li Bian. Bronsted acid-surfactant-combined catalyst for the Mannich reaction in water[J]. Royal society of Chemistry,2014(4): 727~731.
    [16]方东,刘祖亮. 新型功能化离子液体催化水相Mannich反应[M]. 南京航空航天大学学报,2007,39(4): 541~543.
    [17]刘宝友,许丹倩,罗书平等. Bronsted酸离子液体催化的醛、酮、胺三组分Mannich反应[M]. 化工学报,2004,55(12): 2043~2046.
    [18]Ezzat Rafiee,Sara Eavani. H3PW12O40 supported on silica-encapsulated c-Fe2O3nanoparticLes: anovel magnetically-recoverable catalyst for three-component Mannich-typereactions in water[J]. Green Chemistry,2011,12,2116~2122.
    [19]Min Zhang, Biao Xiong,Wei Yang. Highly efficient one-pot,three-component synthesis of β-aminoketones catalyzed by Fe(O2CCF3)3[J]. Synthetic Communications,2012,42,2831~2843.
    [20]MeiWu,Huanwang Jing,Tao Chang. Synthesis of β-amina carbonyl compounds via a Mannich reaction catalyzed by SalenZn complex[J]. Catalysis Communications 2007,8,2217~2221.
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