- 上一篇：张紧轮成型工艺及注射模设计文献综述和参考文献
- 下一篇：聚苯胺制备文献综述和参考文献
图2.4 过氧甲酸氧化3-蒈烯
2.7.4 氧气氧化
分子氧（氧气或空气）既廉价又绿色环保，在所有环氧化烯烃的制备中是最理想的氧源。但三线态的分子氧非常稳定，直接氧化单线态的烯烃十分困难，必须经过共还原剂活化或适当的催化作用才能使烯烃快速环氧化。
徐永军等[47]使用含二价镍的Ni( bpy)2Cl2催化剂, 以氧气作为氧源环氧化苯乙烯, 苯乙烯的转化率可达100%，环氧苯乙烷的选择性达81%, 但催化剂经两次循环后活性明显降低。Ire等[48]在甲腈中以亚碘酰苯氧化1, 2-二苯乙烯, 产率达95%, 选择性为48%。
参考文献
[1] 宋少飞,胡道道,沈淑坤.过氧化氢催化氧化绿色化学研究进展[J].世界科技研究与发展, 2006, 28(2): 20-29.
[2] 佘远斌,王兰芝,宋旭峰,张燕惠,陈一霞.金属卟啉类仿生催化剂的合成、构效关系及在催化氧化碳氢化合物中的应用[J].精细化工,2005, 22(6): 401-408.
[3] Liu Z L, Huang J W, Ji L N. The Preparation of Some Polystyrene-support Eporphydrinatoiron (Ⅲ) and their Catalysis in Hydroxylation of Cyclohexane with Molecular Oxygen [J]. J. Mol. Catal. A Chem., 1996, 104: L193-L196.
[4] 李东红,陈淑华.卟啉类人工受体研究进展[J].化学研究与应用.1988，10: 456-463.
[5] 董润安,邱勇,宋心琦.卟啉类化合物对生物分子的光敏氧化[J].化学进展,
1998(1): 45-54.
[6] Hasart A, Johan E V. Metal Complexes as Photo and Radio Sensitizers [J]. Chem. Rev, 1999, 99: 2373-2450.
[7] Hui L, Xue-Bin S, Mu-Xin Jia, Xi-Kui J, Zhan-Ting L, and Guang-Ju C. Selective Recognition of Sodium Cyanide and Potassium Cyanide by Diaza-crown Ether-crapped Zn-porphyrin Receptors in Polar Solvents[J]. Tetrahedron, 2005, 61: 8095-8100.
[8] Bell T D M, Ghiggino K P, Jolliffe K A, etal. Phtoinduced Energy and Electron Transfer in A Giant Zinc Porphyrin; Bridge; C60 System [J]. J. Phys. Chem. A, 2002, 106: 7958-7970.
[9] Kuroda Y, Kawashima A, Hayashi Y, Ogoshi H. Self-organized Porphyrin Dimer as A Highly Specific Receptor for Pyrazine Derivatives[J] J. Am. Chem. Soc., 1997, 119: 4929-4933.
[10] Anastas P T, Warner J C. Green Chemistry: Theory and Practice [M]. New York: Oxford University Press, Inc., 1998.
[11] Bernard M, Samuel P, de Visser S S. Mechanism of Oxidation Reaction Catalyzed by Cytochrome P-450 Enzymes [J]. Chem. Rev. 2004, 104: 3947-3980.
[12] Calzavara-Pinton P G, Venturini M, Sala R. A Comprehensive Overview of Photo-dynamic Therapy in The Treatment of Superficial Fungal Infections of the skin [J]. J. Photochemistry and Photobiology B: Biology. 2005, 78(1): 1-6.
[13] 张智,向军辉,赵福群,等.染料分子结构对光付器件性能的影响[J]. 化学通报, 2006 (3): 173-178.
[14] 委福祥,曹进,张晓波,等.新型苯乙烯衍生物掺杂的蓝色及白色有机电致发光器件[J].物理学报, 2006, 55(4): 2008-2013.
[15] Huang J L, Chen N S, Huang J D. Synthesis, Peculiarity and Anti-tumor Potency of the Double Affinity Photosensitizer-zinc Phthalocanine [J]. Sci Chin (Series B), 2000, 30(3): 48-488.
[16] Baraton. S, Coutanceau. C, Leger. J.-M, etal. Altermative Cathodes Based on Ironphth-alocyanine Catalysts for Mini-or Micro-DMFC Working at Roomtem Perature[J]. Electrochimica Acta, 2005, 51(3): 517-525.
[17] Feng Zhao, Falk Harnisch, Uwe Schroder,etal. Application of Pyrosediron(II) Phth-alocyanine and CoTMPP Based Oxygen Reduction Catalysts as Cathode Materials in Microbial Fuel Cell[J].Electrochemistry Communications, 2005, 7(12): 1405-1410.
[18] Nthapo Sehlotho, Tebbello Nyokong. Zincphthalo Cyanine Photocatalyzed Oxidation of Cyclohexene[J].Journal of Molecular Catalysis A: chemical, 2004, 219 (2):201-207.
[19] Mario Calvete, Guo Ying Yang,Michael Hanack,Porphyrins and Phthalocyanines
as Materials for Optical Limiting[J].Synthetic Metals, 2004, 141(3): 231-243.
[20] Martin. G, Martinez-Diaz. M. V, de la Torre. G, etal. Triazolehemiporphyrazines as Bridging Paths in Push-pull Phthalocyanines for Quadratic Nonlinear Optics[J].